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The dynamics of the H+D₂O→OD+HD reaction at 2.5 eV: experiment and theory

Brouard, M.; Burak, I; Minayev, D.; O'Keeffe, P.; Vallance, C.; Aoiz, F. J.; Bañares, L.; Castillo, J. F.; Zhang, Dong H.; Collins, Michael A.


The title reaction has been studied both experimentally and computationally at a mean collision energy of 2.48 eV. OD quantum state populations, rotational alignment parameters, rovibrational quantum state-resolved center-of-mass angular scattering distributions and HD co-product internal energy release distributions have been determined, along with OD quantum state averaged energy disposals. The experiments employ pulsed laserphotolysis coupled with polarized Doppler-resolved laser induced...[Show more]

CollectionsANU Research Publications
Date published: 2003-01-15
Type: Journal article
Source: The Journal of Chemical Physics
DOI: 10.1063/1.1528896


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