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Experimental verification of line- and band-shape asymmetry in the Schumann–Runge system of O[sub 2]

Kono, M; Lewis, B. R; Baldwin, Kenneth; Gibson, S. T


High-resolution, laser-based photoabsorption cross-section measurements in the weakly absorbing windows between the (11,0) and (16,0) Schumann–Runge bands of O₂ have been performed at liquid-nitrogen temperature and the results compared with corresponding coupled-channel Schrödinger-equation (CSE) and line-by-line model calculations. While the symmetric-line- shape-based line-by-line model cross sections differ significantly from experiment, the excellent agreement found between the CSE and...[Show more]

CollectionsANU Research Publications
Date published: 2003-06-22
Type: Journal article
Source: The Journal of Chemical Physics
DOI: 10.1063/1.1574512


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