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The Kawasaki identity and the Fluctuation Theorem

Carberry, D. M.; Williams, S. R.; Wang, G. M.; Sevick, E. M.; Evans, Denis J.


In this paper we show that the Fluctuation Theorem of Evans and Searles [D. J. Evans, D. J. Searles, Phys. Rev. E 50, 1645 (1994)] implies that the Kawasaki function is unity for all time t. We confirm this relationship using experimental data obtained using optical tweezers, and show that the Kawasaki function is a valuable diagnostic tool.

CollectionsANU Research Publications
Date published: 2004-11-01
Type: Journal article
Source: The Journal of Chemical Physics
DOI: 10.1063/1.1802211


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