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Numerical study of the Steady State Fluctuation Relations Far from Equilibrium

Williams, Stephen R.; Searles, Debra J.; Evans, Denis J.

Description

A thermostatted dynamical model with five degrees of freedom is used to test the fluctuation relation of Evans and Searles (Ω-FR) and that of Gallavotti and Cohen (Λ-FR). In the absence of an external driving field, the model generates a time-independent ergodic equilibrium state with two conjugate pairs of Lyapunov exponents. Each conjugate pair sums to zero. The fluctuation relations are tested numerically both near and far from equilibrium. As expected from previous work, near equilibrium...[Show more]

CollectionsANU Research Publications
Date published: 2006-05-15
Type: Journal article
URI: http://hdl.handle.net/1885/15787
Source: Journal of Chemical Physics
DOI: 10.1063/1.2196411

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