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Emergent magnetism from lithium freezing in lithium-doped boron nitride

Berlie, Adam; White, John; Henderson, Mark; Cottrell, S P


The synthesis and characterization of Li-doped boron nitride is reported where the sample is in the dilute limit with a stoichiometry of Li-0.01(BN)(3). The diffusion of atomic Li dominates above 150 K, with D-Li similar to 10(-10) cm(2)s(-1), where the Li diffusion rate increases with temperature resulting in activated behavior with an energy scale of 27 meV. Below 150 K the Li diffusion freezes out and the sample enters a magnetic state at approximately 70 K that shows evidence for being...[Show more]

CollectionsANU Research Publications
Date published: 2017
Type: Journal article
Source: Physical Review Materials
DOI: 10.1103/PhysRevMaterials.1.054405
Access Rights: Open Access


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