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External-Template-Assisted Formation of Octacyanometalate-Based MV-MnII(M = W, Mo) Bimetallic Coordination Polymers with Magnetic Properties

Qian, Jun; Hu, Jingchun; Yoshikawa, Hirofumi; Zhang, Jinfang; Awaga, Kunio; Zhang, Chi


Three manganese–molybdenum/tungsten bimetallic coordination polymers, two 2D {{[μ4-M(CN)8]2[Mn(dmf)3]2[Mn(dmf)4]}·2DMF}n (M = W 1, Mo 2) and a 1D {{[μ4-Mo(CN)8][Mn(dmf)4]2}·(ClO4)}n (3), were constructed from the reaction of the (Bu3NH)3[M(CN)8] (M = W, Mo) and Mn(ClO4)2·6H2O molecular building blocks in DMF solvent in the presence (for 1 and 2) or absence (for 3) of the organic ligand bis(benzimidazol-2′-yl)pyridine. Single-crystal X-ray diffraction structure analysis indicated that compounds...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: European Journal of Inorganic Chemistry
DOI: 10.1002/ejic.201403223


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