Skip navigation
Skip navigation

Metal oxidation states in biological water splitting

Krewald, Vera; Retegan, Marius; Cox, Nicholas; Messinger, J; Lubitz, Wolfgang; DeBeer, Serena; Neese, Frank; Pantazis, Dimitrios A.

Description

A central question in biological water splitting concerns the oxidation states of the manganese ions that comprise the oxygen-evolving complex of photosystem II. Understanding the nature and order of oxidation events that occur during the catalytic cycle of five Si states (i = 0–4) is of fundamental importance both for the natural system and for artificial water oxidation catalysts. Despite the widespread adoption of the so-called “high-valent scheme”—where, for example, the Mn oxidation states...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
URI: http://hdl.handle.net/1885/153574
Source: Chemical Science
DOI: 10.1039/C4SC03720K
Access Rights: Open Access

Download

File Description SizeFormat Image
01_Krewald_Metal_oxidation_states_in_2015.pdf2.07 MBAdobe PDFThumbnail


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  22 January 2019/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator