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A hybrid ruthenium alkynyl/zinc porphyrin "Cross Fourchée" with large cubic NLO properties

Merhi, Areej; Grelaud, Guillaume; Green, Katy A; Minh, Ngo Hoang; Reynolds, Michael; Ledoux, Isabelle; Barlow, Adam; Wang, Genmiao; Cifuentes, Marie P; Humphrey, Mark; Paul, Frédéric; Paul-Roth, Christine O

Description

A new Zn(ii) porphyrin-cored ruthenium alkynyl dendrimer (2) containing twelve Ru(κ(2)-dppe)2 bis-alkynyl fragments has been prepared in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) and shown to be highly active for third-harmonic generation (THG) at 1907 nm.

CollectionsANU Research Publications
Date published: 2015-05-07
Type: Journal article
URI: http://hdl.handle.net/1885/15293
Source: Dalton transactions
DOI: 10.1039/c5dt00768b

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