Skip navigation
Skip navigation
Open Research will be down for maintenance between 8:00am and 8:15am on Monday, 9th December 2019.

Phosphine, isocyanide, and alkyne reactivity at pentanuclear molybdenum/tungsten-iridium clusters

Simpson, Peter V; Randles, Michael D; Gupta, Vivek; Fu, Junhong; Moxey, Graeme J; Schwich, Torsten; Morshedi, Mahbod; Cifuentes, Marie P; Humphrey, Mark


The trigonal bipyramidal clusters M2Ir3(μ-CO)3(CO)6(η(5)-C5H5)2(η(5)-C5Me4R) (M = Mo, R = Me 1a, R = H; M = W, R = Me, H) reacted with isocyanides to give ligand substitution products M2Ir3(μ-CO)3(CO)5(CNR′)(η(5)-C5H5)2(η(5)-C5Me4R) (M = Mo, R = Me, R′ = C6H3Me2-2,6 3a; M = Mo, R = Me, R′ = (t)Bu 3b), in which core geometry and metal atom locations are maintained, whereas reactions with PPh3 afforded M2Ir3(μ-CO)4(CO)4(PPh3)(η(5)-C5H5)2(η(5)-C5Me4R) (M = Mo, R = Me 4a, H 4c; M = W, R = Me 4b,...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c5dt00525f


File Description SizeFormat Image
01 Simpson et al Phosphine isocyanide and 2015.pdf2.38 MBAdobe PDFThumbnail

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  22 January 2019/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator