Cyclodextrin-based rotaxanes for material science applications
In the work described in this thesis, CD-based rotaxanes were prepared and their solid-state structures/packing, morphology and crystal growth behaviour were explored. Encapsulation of profluorescent nitroxides through rotaxane formation demonstrated the use of CD-based rotaxanes to change the reactivity of CD guests and therefore preserve their properties. In Chapter 2, the rotaxane 1.17 having a stilbene-based axle and 3,5-dimethylaniline blocking groups, as well as the rotaxane 1.18 having...[Show more]
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