Organometallic routes to cross-conjugated hydrocarbons
Molecules with a high degree of unsaturation often have associated with them a concomitant level of instability. In fact, their instability is what hinders the preparation and synthetic utility of large swaths of polyunsaturated frameworks. One form of modulating and controlling that reactivity is the tricarbonyliron group; a functionality that coordinates to a portion of an unsaturated skeleton, often allowing the easy isolation and observation of the unstable compound. This thesis explores...[Show more]
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