gem-Dihalocyclopropanes as precursors to alkaloidal ring systems
gem-Dihalocyclopropanes (1) are an important class of compound that play significant roles in contemporary organic synthesis. This is largely due to their ease of preparation, (which is normally accomplished via addition of the relevant dihalocarbene to an alkene), and the wide range of reactions they can undergo. These reactions can be divided into two broad subgroups, those that proceed with retention of the three membered ring, and those where one of the C-C bonds is broken, thus leading to...[Show more]
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