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Functionalising transition metal carbynes with main group elements

Shang, Rong

Description

A lithiocarbyne complex Tp*(CO){u2082}Mo{u2261}CLi (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) can be generated in situ from treatment of a THF solution of the bromocarbyne complex Tp*(CO){u2082}Mo{u2261}CBr with one equivalent of nBuLi at - 78 {u00B0} Celsius. It shows versatile reactivities towards a wide range of electrophiles and serves as an excellent starting material for many heteroatom substituted carbyne complexes, many of which were previously inaccessible from conventional...[Show more]

CollectionsOpen Access Theses
Type: Thesis (PhD)
URI: http://hdl.handle.net/1885/149827

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