Synthesis and Diels-Alder Reactivity of Substituted Dendralenes
The first synthesis of all five possible monomethylated dendralenes has been achieved via two distinct synthetic strategies. The Diels-Alder chemistry of these new dendralenes (as multidienes) with an electron poor dienophile, N-methylmaleimide (NMM), has been studied. Thus, simply upon mixing the dendralene and an excess of dienophile at ambient temperature in a common solvent, sequences of cycloadditions result in the rapid generation of complex multicyclic products. Distinct product...[Show more]
|Collections||ANU Research Publications|
|Source:||The Journal of organic chemistry|
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