Discovery and Computational Rationalization of Diminishing Alternation in [n]Dendralenes
The [n]dendralenes are a family of acyclic hydrocarbons which, by virtue of their ability to rapidly generate structural complexity, have attracted significant recent synthetic attention. Dendralene through dendralene have been previously prepared but no higher member of the family has been reported to date. Here, we describe the first chemical syntheses of the "higher" dendralenes, dendralene through dendralene. We also report a detailed investigation into the spectroscopic...[Show more]
|Collections||ANU Research Publications|
|Source:||Journal of the American Chemical Society|
|Access Rights:||Open Access|
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