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A Domino Diels-Alder Approach toward the Tetracyclic Nicandrenone Framework

Mackay, Emily G; Nörret, Marck; Wong, Leon S-M; Louis, Ignace; Lawrence, Andrew L; Willis, Anthony C; Sherburn, Michael

Description

The tetracarbocyclic framework of the nicandrenone natural products is formed in one step from a linear precursor via a domino intramolecular Diels-Alder/intramolecular furan Diels-Alder/aromatization sequence. The approach represents a new 0 → ABCD strategy for the preparation of aromatic steroids.

CollectionsANU Research Publications
Date published: 2015-11-20
Type: Journal article
URI: http://hdl.handle.net/1885/149536
Source: Organic letters
DOI: 10.1021/acs.orglett.5b02412
Access Rights: Open Access

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