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[5]Radialene

Mackay, Emily G; Newton, Christopher G; Toombs-Ruane, Henry; Lindeboom, Erik; Fallon, Thomas; Willis, Anthony C; Paddon-Row, Michael N; Sherburn, Michael

Description

The [n]radialenes are a unique family of fundamental [n]-membered carbocyclic structures with radiating alkenes, which have attracted significant synthetic and theoretical attention. Whereas [3]-, [4]-, and [6]radialenes have been prepared and studied, all efforts to synthesize the five-membered ring compound have thus far met with failure. Here we describe the first synthesis of the fundamental hydrocarbon [5]radialene, C10H10. Our approach was a departure from previous radialene syntheses in...[Show more]

CollectionsANU Research Publications
Date published: 2015-11-25
Type: Journal article
URI: http://hdl.handle.net/1885/149535
Source: Journal of the American Chemical Society
DOI: 10.1021/jacs.5b07445

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