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Selenoxopropadienylidene (CCCSe) as a bridging ligand

Hill, Anthony F.; Manzano, Richard A.; Sharma, Manab; Ward, Jas S.

Description

The reaction of [W(≡CC≡CSiMe3)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [nBu4N]F and selenium in the presence of [RuCl(PPh3)2(η-C5H5)] affords a mixture of the tricarbido complex [WRu(μ-CCC)(CO)2(PPh3)2(η-C5H5)(Tp*)] and the selenoxopropadienylidene (C3Se) complex [WRu(μ-CCCSe)(CO)2(PPh3)2(η-C5H5)(Tp*)], both of which were structurally characterized. The formation of the bimetallic C3Se complex is consistent with the intermediacy of the salt [nBu4N]...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
URI: http://hdl.handle.net/1885/14881
Source: Organometallics
DOI: 10.1021/om5011534

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