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Iron and Ruthenium Alkynyl Complexes with 2-Fluorenyl Groups: Some Linear and Nonlinear Optical Absorption Properties

Malvolti, Floriane; Rouxel, Cedric; Grelaud, Guillaume; Toupet, Loic; Roisnel, Thierry; Barlow, Adam; Yang, Xinwei; Wang, Genmiao; Abdul Razak, Fazira I.; Stranger, Robert; Cifuentes, Marie P.; Humphrey, Mark; Mongin, Olivier; Blanchard-Desce, Mireille; Paul-Roth, Christine O.; Paul, Frédéric


Four new mononuclear alkynyl complexes each featuring a terminal 2‐fluorenyl group, namely Fe(η5‐C5Me5)(CO)2[C≡C(2‐C21H25)] (2), Ru(κ2‐dppe)2Cl[C≡C(2‐C21H25)] (3), Ru(κ2‐dppe)2[C≡C(4‐C6H4NO2)][C≡C(2‐C21H25)] (4), and [Fe(η5‐C5Me5)(κ2‐dppe){C≡C(C5H4N)‐CH2(2‐C13H9)}][PF6] (5[PF6]), have been synthesized and characterized, and their redox, absorption, and emission properties have been studied. For the two ruthenium derivatives 3 and 4, these studies are complemented by spectroelectrochemical...[Show more]

CollectionsANU Research Publications
Date published: 2016
Type: Journal article
Source: European Journal of Inorganic Chemistry
DOI: 10.1002/ejic.201600598


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