Skip navigation
Skip navigation

Binuclear Sulfide Niobium Clusters Coordinated by Diimine Ligands: Synthesis, Structure, Photocatalytic Activity and Optical Limiting Properties

Rogachev, Alexander V.; Gushchin, Artem L.; Abramov, Pavel A.; Kozlova, Ekaterina A.; Vicent, Cristian; Piryazev, Dmitry; Barlow, Adam; Samoc, Marek; Humphrey, Mark; Llusar, Rosa; Fedin, Vladimir P.; Sokolov, Maxim N.

Description

Substitution reactions of binuclear niobium cluster anion [Nb2S4(NCS)8]4– with different types of pyridine‐based diimine ligands have been carried out. In the case of 2,2′‐bipyridine (bipy) and its derivatives, only monosubstituted complexes [Nb2S4(NCS)6L]2– have been isolated. In the case of 1,10‐phenanthroline and 2‐(2‐pyridyl)benzimidazole (Hpbz), both mono‐ and disubstituted complexes, [Nb2S4(NCS)6L]2– and [Nb2S4(NCS)4L2], respectively, have been obtained. Crystal structures of...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
URI: http://hdl.handle.net/1885/148196
Source: European Journal of Inorganic Chemistry
DOI: 10.1002/ejic.201500319
Access Rights: Open Access

Download

File Description SizeFormat Image
Rogachev_et_al-2015-European_Journal_of_Inorganic_Chemistry.pdf3.65 MBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  22 January 2019/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator