Binuclear Sulfide Niobium Clusters Coordinated by Diimine Ligands: Synthesis, Structure, Photocatalytic Activity and Optical Limiting Properties
-
Altmetric Citations
Rogachev, Alexander V.; Gushchin, Artem L.; Abramov, Pavel A.; Kozlova, Ekaterina A.; Vicent, Cristian; Piryazev, Dmitry; Barlow, Adam; Samoc, Marek; Humphrey, Mark; Llusar, Rosa; Fedin, Vladimir P.; Sokolov, Maxim N.
Description
Substitution reactions of binuclear niobium cluster anion [Nb2S4(NCS)8]4– with different types of pyridine‐based diimine ligands have been carried out. In the case of 2,2′‐bipyridine (bipy) and its derivatives, only monosubstituted complexes [Nb2S4(NCS)6L]2– have been isolated. In the case of 1,10‐phenanthroline and 2‐(2‐pyridyl)benzimidazole (Hpbz), both mono‐ and disubstituted complexes, [Nb2S4(NCS)6L]2– and [Nb2S4(NCS)4L2], respectively, have been obtained. Crystal structures of...[Show more]
Collections | ANU Research Publications |
---|---|
Date published: | 2015 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/148196 |
Source: | European Journal of Inorganic Chemistry |
DOI: | 10.1002/ejic.201500319 |
Access Rights: | Open Access |
Download
File | Description | Size | Format | Image |
---|---|---|---|---|
MGH272-preprint.pdf | 2.54 MB | Adobe PDF | ![]() |
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.
Updated: 17 November 2022/ Responsible Officer: University Librarian/ Page Contact: Library Systems & Web Coordinator