A Biomimetic Total Synthesis of the Alkaloid Gracilamine
In 2005 Ünver and Kaya reported that ethanolic extraction of the dried and powdered total plant material derived from Galanthus gracilis, a Turkish member of the Amaryllidaceae family, lead to the isolation of gracilamine and to which the unprecedented structure 1.1 was assigned on the basis of extensive NMR spectroscopic and mass spectrometric analyses. This compound represents the first example of a pentacyclic dinitrogenous alkaloid isolated...[Show more]
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