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Entropy driven chain effects on ligation chemistry

Pahnke, Kai; Brandt, Josef; Gryn'ova, Ganna; Lindner, Peter; Schweins, Ralf; Schmidt, Friedrich Georg; Lederer, Albena; Coote, Michelle; Barner-Kowollik, Christopher


We report the investigation of fundamental entropic chain effects that enable the tuning of modular ligation chemistry – for example dynamic Diels–Alder (DA) reactions in materials applications – not only classically via the chemistry of the applied reaction sites, but also via the physical and steric properties of the molecules that are being joined. Having a substantial impact on the reaction equilibrium of the reversible ligation chemistry, these effects are important when transferring...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Chemical Science
DOI: 10.1039/C4SC02908A
Access Rights: Open Access


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