Entropy driven chain effects on ligation chemistry
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Pahnke, Kai; Brandt, Josef; Gryn'ova, Ganna; Lindner, Peter; Schweins, Ralf; Schmidt, Friedrich Georg; Lederer, Albena; Coote, Michelle; Barner-Kowollik, Christopher
Description
We report the investigation of fundamental entropic chain effects that enable the tuning of modular ligation chemistry – for example dynamic Diels–Alder (DA) reactions in materials applications – not only classically via the chemistry of the applied reaction sites, but also via the physical and steric properties of the molecules that are being joined. Having a substantial impact on the reaction equilibrium of the reversible ligation chemistry, these effects are important when transferring...[Show more]
Collections | ANU Research Publications |
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Date published: | 2015 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/13525 |
Source: | Chemical Science |
DOI: | 10.1039/C4SC02908A |
Access Rights: | Open Access |
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File | Description | Size | Format | Image |
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Pahnke K et al Entropy driven chain effects 2015.pdf | Published version | 2.42 MB | Adobe PDF |
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