Entropy driven chain effects on ligation chemistry
We report the investigation of fundamental entropic chain effects that enable the tuning of modular ligation chemistry – for example dynamic Diels–Alder (DA) reactions in materials applications – not only classically via the chemistry of the applied reaction sites, but also via the physical and steric properties of the molecules that are being joined. Having a substantial impact on the reaction equilibrium of the reversible ligation chemistry, these effects are important when transferring...[Show more]
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|Pahnke K et al Entropy driven chain effects 2015.pdf||Published version||2.42 MB||Adobe PDF|
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