Pahnke, Kai; Brandt, Josef; Gryn'ova, Ganna; Lindner, Peter; Schweins, Ralf; Schmidt, Friedrich Georg; Lederer, Albena; Coote, Michelle; Barner-Kowollik, Christopher
We report the investigation of fundamental entropic chain effects that enable the tuning of modular ligation
chemistry – for example dynamic Diels–Alder (DA) reactions in materials applications – not only classically
via the chemistry of the applied reaction sites, but also via the physical and steric properties of the molecules
that are being joined. Having a substantial impact on the reaction equilibrium of the reversible ligation
chemistry, these effects are important when transferring...[Show more]
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