Nanocompartmentalization of soft materials with three mutually immiscible solvents: synthesis and self-assembly of three-arm star-polyphiles
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de Campo, Liliana; Moghaddam, Minoo J.; Varslot, Trond; Kirby, Nigel; Mittelbach, Rainer; Sawkins, Tim; Hyde, Stephen T.
Description
We report synthesis, thermotropic, and lyotropic mesomorphism of a family of novel “star-polyphiles”: small star-shaped molecules bearing three mutually immiscible arms, hydrophilic (oligoethylene glycol), oleophilic (alkanes), and fluorophilic (perfluorinated alkanes), attached to a central 1,3,5-trihydroxybenzene core. A facile, flexible multistep synthesis giving high-purity yields of 14 distinct members of the family is described, with variable arm lengths, forming crystalline, or...[Show more]
Collections | ANU Research Publications |
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Date published: | 2015-01-06 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/13123 |
Source: | Chemistry of Materials |
DOI: | 10.1021/cm503981t |
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