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Cyclopalladated complexes containing 2-C6R4PPh2 ligands (R = H, F): one-electron electrochemical reduction leading to metal-carbon σ-bond cleavage via palladium(I)

Kar, Gopa; Privér, Steven H; Jones, Lathe A; Guo, Si-Xuan; Torriero, Angel A J; Bond, Alan M; Bennett, Martin A; Bhargava, Suresh K


Three new ortho-metallated palladium complexes, [Pd(O,O'-hfacac)(κ(2)-2-C6F4PPh2)] (), [Pd2(O,O'-hfacac)2(μ-2-C6F4PPh2)2] () and [Pd(O,O'-hfacac)(κC-2-C6F4PPh2)(PPh3)] () (hfacac = hexafluoroacetylacetonate), have been prepared and fully characterised. The electrochemical reductions of complexes , together with those of other cyclopalladated complexes containing 2-C6R4PPh2 ligands (R = H, F) were studied by cyclic, rotating disk and microelectrode voltammetry. Evidence for the one-electron...[Show more]

CollectionsANU Research Publications
Date published: 2015-02-21
Type: Journal article
Source: Dalton transactions
DOI: 10.1039/c4dt03268c


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