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Synthesis, structural, electrochemical, and spectroscopic studies of some (diimine)ruthenium nitrile complexes

Babgi, Bandar; Asiri, Abdullah M; Arshad, Muhammad Nadeem; Humphrey, Mark

Description

The syntheses of cationic ruthenium(II) complexes [Ru(Me₂-bpy)(PPh₃)₂RRʹ][PF₆]x {Me₂-bpy = 4,4ʹ-dimethyl-2,2ʹ-bipyridine, (3) R = Cl, Rʹ = N≡CMe, x = 1, (4) R = Cl, Rʹ = N≡CPh, x = 1, (5) R = Rʹ = N≡CMe, x = 2} and [Ru(Me₂-bpy)(κ²-dppf)RRʹ][PF₆]x {dppf = 1,1ʹ-bis(diphenylphosphino)ferrocene, (6) R = Cl, Rʹ = N≡CMe, x = 1, (7) R = Cl, Rʹ = N≡CPh, x = 1, (8) R = Rʹ = N≡CMe, x = 2} are reported, together with their structural confirmation by NMR (31P, 1H) and IR spectroscopy and elemental...[Show more]

CollectionsANU Research Publications
Date published: 2015-02-23
Type: Journal article
URI: http://hdl.handle.net/1885/12963
Source: Journal of Coordination Chemistry
DOI: 10.1080/00958972.2015.1012073

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