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RAFT-based polystyrene and polyacrylate melts under thermal and mechanical stress

Coote, Michelle; Altintas, O.; Riazi, K.; Lee, R.; Lin, C.Y.; Wilhelm, M.; Barner-Kowollik, C.


Although controlled/living radical polymerization processes have significantly facilitated the synthesis of well-defined low polydispersity polymers with specific functionalities, a detailed and systematic knowledge of the thermal stability of the products-highly important for most industrial processes-is not available. Linear polystyrene (PS) carrying a trithiocarbonate mid-chain functionality (thus emulating the structure of the Z-group approach via reversible addition-fragmentation chain...[Show more]

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Macromolecules 46.20 (2013): 8079-8091
DOI: 10.1021/ma401749h
Access Rights: Open Access


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