Self-Assembly of Square-Planar Halide Complexes of Trimethylphosphine-Stabilized Diphenyl-Arsenium, -Stibenium, and -Bismuthenium Hexafluorophosphates
Square-planar halide complexes in which four trimethylphosphine-stabilized diphenyl-stibenium or-bismuthenium ions surround a central halide ion in discrete centrosymmetrical structures of C₄h symmetry have been isolated and their structures determined by X-ray crystallography. The structures are stabilized by electrostatic interactions between the halide ion and four positively charged trimethylphosphine-stabilized diphenyl-stibenium or-bismuthenium ions, as well as four edge-to-face...[Show more]
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|Source:||Australian Journal of Chemistry|
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