Self-Assembly of Square-Planar Halide Complexes of Trimethylphosphine-Stabilized Diphenyl-Arsenium, -Stibenium, and -Bismuthenium Hexafluorophosphates
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Wielandt, J. Wolfram; Petrie, Simon; Kilah, Nathan L.; Willis, Anthony C.; Dewhurst, Rian D.; Belaj, Ferdinand; Orthaber, Andreas; Stranger, Robert; Wild, S. Bruce
Description
Square-planar halide complexes in which four trimethylphosphine-stabilized diphenyl-stibenium or-bismuthenium ions surround a central halide ion in discrete centrosymmetrical structures of C₄h symmetry have been isolated and their structures determined by X-ray crystallography. The structures are stabilized by electrostatic interactions between the halide ion and four positively charged trimethylphosphine-stabilized diphenyl-stibenium or-bismuthenium ions, as well as four edge-to-face...[Show more]
Collections | ANU Research Publications |
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Date published: | 2016-01-28 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/112348 |
Source: | Australian Journal of Chemistry |
DOI: | 10.1071/CH15701 |
Access Rights: | Open Access |
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