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Self-Assembly of Square-Planar Halide Complexes of Trimethylphosphine-Stabilized Diphenyl-Arsenium, -Stibenium, and -Bismuthenium Hexafluorophosphates

Wielandt, J. Wolfram; Petrie, Simon; Kilah, Nathan L.; Willis, Anthony C.; Dewhurst, Rian D.; Belaj, Ferdinand; Orthaber, Andreas; Stranger, Robert; Wild, S. Bruce

Description

Square-planar halide complexes in which four trimethylphosphine-stabilized diphenyl-stibenium or-bismuthenium ions surround a central halide ion in discrete centrosymmetrical structures of C₄h symmetry have been isolated and their structures determined by X-ray crystallography. The structures are stabilized by electrostatic interactions between the halide ion and four positively charged trimethylphosphine-stabilized diphenyl-stibenium or-bismuthenium ions, as well as four edge-to-face...[Show more]

CollectionsANU Research Publications
Date published: 2016-01-28
Type: Journal article
URI: http://hdl.handle.net/1885/112348
Source: Australian Journal of Chemistry
DOI: 10.1071/CH15701

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