Skip navigation
Skip navigation

Deprotonation of Water Ligands in V, Cr, Mn, Fe, and Co Complexes Reduces Oxidation-Driven Carboxylate Ligand Frequency Shifts

Chuah, Wooi Yee; Frankcombe, Terry J


In Mn complexes, it has been shown that oxidation-driven changes in carboxylate ligand vibrations are suppressed, if a water or hydroxo ligand is simultaneously deprotonated. Deprotonation with oxidation has also been shown to greatly reduce the dependence of Mn complex redox energies on the oxidation state of the metal. We have here investigated the effect of oxidation with deprotonation on the carboxylate ligand frequencies of V, Cr, Mn, Fe, and Co complexes. The effects of anionic ligand...[Show more]

CollectionsANU Research Publications
Date published: 2016-03-10
Type: Journal article
Source: The journal of physical chemistry. B
DOI: 10.1021/acs.jpcb.6b00168
Access Rights: Open Access


There are no files associated with this item.

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  17 November 2022/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator