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Deprotonation of Water Ligands in V, Cr, Mn, Fe, and Co Complexes Reduces Oxidation-Driven Carboxylate Ligand Frequency Shifts

Chuah, Wooi Yee; Frankcombe, Terry J

Description

In Mn complexes, it has been shown that oxidation-driven changes in carboxylate ligand vibrations are suppressed, if a water or hydroxo ligand is simultaneously deprotonated. Deprotonation with oxidation has also been shown to greatly reduce the dependence of Mn complex redox energies on the oxidation state of the metal. We have here investigated the effect of oxidation with deprotonation on the carboxylate ligand frequencies of V, Cr, Mn, Fe, and Co complexes. The effects of anionic ligand...[Show more]

CollectionsANU Research Publications
Date published: 2016-03-10
Type: Journal article
URI: http://hdl.handle.net/1885/111978
Source: The journal of physical chemistry. B
DOI: 10.1021/acs.jpcb.6b00168

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