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Indirect predissociation of highly excited singlet states of N₂

Heays, A.N.; Lewis, B.R.; Gibson, S.T.; Stark, G.; de Oliveira, N.

Description

Indirect predissociation of the b′¹Σu⁺(v = 20) level of N₂ is studied experimentally by vacuum-ultraviolet photoabsorption employing synchrotron radiation and a Fourier-transform spectrometer, and interpreted with the aid of a quantitative model of interacting ¹∏u and ¹Σu⁺, bound and unbound states which solves the coupled Schrödinger equation. An observed rotationally-localised peak in the b′(20) predissociation linewidths is identified by the model as arising from an interaction with a...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
URI: http://hdl.handle.net/1885/111416
Source: EPJ Web of Conferences: 9th International Conference on Dissociative Recombination: Theory, Experiment, and Applications, DR 2013; FIAP Jean Monnet Convention CentreParis; France; 7 July 2013 through 12 July 2013
DOI: 10.1051/epjconf/20158403004

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