Skip navigation
Skip navigation

Rare events out of equilibrium: mobility through the liquid–liquid interface

Williams, Stephen R.


Transition state theory provides a well established means to compute the rate at which rare events occur; however, this is strictly an equilibrium approach. Here we consider a nonequilibrium problem of this nature in the form of transport through a liquid–liquid interface. When two immiscible liquids are coexisting in equilibrium, there will be a certain amount of mixing between the two phases, resulting in a finite linear mobility across the liquid–liquid interface. We derive an exact...[Show more]

CollectionsANU Research Publications
Date published: 2016
Type: Journal article
Source: Molecular Simulation
DOI: 10.1080/08927022.2015.1112007


There are no files associated with this item.

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  23 August 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator