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Anion-templated 2D frameworks from hexahydroxytriphenylene

Morshedi, Mahbod; Willis, Anthony C.; White, Nicholas G.

Description

Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H⋯anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO₄⁻ was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO₃⁻).

CollectionsANU Research Publications
Date published: 2016
Type: Journal article
URI: http://hdl.handle.net/1885/108626
Source: CrystEngComm
DOI: 10.1039/C6CE00297H

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