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Metallophilic Contacts in 2-C 6 F 4 PPh 2 Bridged Heterobinuclear Complexes: A Crystallographic and Computational Study

Wachtler, Erik; Priver, Steven H; Wagler, Jorg; Heine, Thomas; Zhechkov, Lyuben; Bennett, Martin; Bhargava, Suresh Kumar

Description

(Figure Presented) Treatment of the bis(chelate) complex trans-[Pd(κ2-2- <inf>6</inf>F<inf>4</inf>PPh<inf>2</inf>)<inf>2</inf>] (7) with PMe<inf>3</inf> gave trans-[Pd(κC-2-C<inf>6</inf>F<inf>4</inf>PPh<inf>2</inf>)<inf>2</inf>(PMe<inf>3</inf>)<inf>2</inf>] (13) as a mixture of syn- and anti-isomers. Reaction of 13 with CuCl, AgCl, or [AuCl(tht)] (tht = tetrahydrothiophene) gave the heterobinuclear complexes...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
URI: http://hdl.handle.net/1885/104023
Source: Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.5b00939

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