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Single cyanide-bridged Mo(W)/S/Cu cluster-based coordination polymers: Reactant- and stoichiometry-dependent syntheses, effective photocatalytic properties

Zhang, Jinfang; Wang, Chao; Wang, Yinlin; Chen, Weitao; Cifuentes, Marie; Zhang, Chi; Humphrey, Mark


The systematic study on the reaction variables affecting single cyanide-bridged Mo(W)/S/Cu cluster-based coordination polymers (CPs) is firstly demonstrated. Five anionic single cyanide-bridged Mo(W)/S/Cu cluster-based CPs {[Pr<inf>4</inf>N][WS<inf>4</inf>Cu<inf>3</inf>(CN)<inf>2</inf>]}<inf>n</inf> (1), {[Pr<inf>4</inf>N][WS<inf>4</inf>Cu<inf>4</inf>(CN)<inf>3</inf>]}<inf>n</inf> (2), {[Pr<inf>4</inf>N][WOS<inf>3</inf>Cu<inf>3</inf>(CN)<inf>2</inf>]}<inf>n</inf> (3),...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Journal of Solid State Chemistry
DOI: 10.1016/j.jssc.2015.08.025
Access Rights: Open Access


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