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Syntheses, Spectroscopic, Electrochemical, and Third-Order Nonlinear Optical Studies of a Hybrid Tris{ruthenium(alkynyl)/(2-phenylpyridine)}iridium Complex

Zhao, Huajian; Simpson, Peter; Barlow, Adam; Moxey, Graeme; Morshedi, Mahbod; Roy, Nivya; Philip, Reji; Zhang, Chi; Cifuentes, Marie; Humphrey, Mark


The synthesis of fac-[Ir{N,C<inf>1</inf>′-(2,2′-NC<inf>5</inf>H<inf>4</inf>C<inf>6</inf>H<inf>3</inf>-5′-ξC-1-C<inf>6</inf>H<inf>2</inf>-3,5-Et<inf>2</inf>-4-ξCC<inf>6</inf>H<inf>4</inf>-4-ξCH)}<inf>3</inf>] (10), which bears pendant ethynyl groups, and its reaction with [RuCl(dppe)<inf>2</inf>]PF<inf>6</inf> to afford the heterobimetallic complex...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Chemistry, A European Journal
DOI: 10.1002/chem.201500951


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