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A ligand field series for the 4f-block from experimental and DFT computed Ce(IV/III) electrochemical potentials

Bogart, Justin A.; Lewis, Andrew J.; Boreen, Michael A.; Lee, Heui Beom; Medling, Scott; Carroll, Patrick J.; Booth, Corwin H.; Schelter, Eric J.

Description

Understanding of the sensitivity of the reduction potential of cerium(IV) cations to ligand field strength has yet to benefit from systematic variation of the ligand environment. Detailed analyses for a series of seven cerium(IV) tetrakis(pyridyl-nitroxide) compounds and their cerium(III) analogues in varying ligand field strengths are presented. Electrochemical, spectroscopic, and computational results reveal a close correlation of electronic properties with ligand substituents. Together...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
URI: http://hdl.handle.net/1885/103048
Source: Inorganic Chemistry
DOI: 10.1021/ic503000z

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