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Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties **

Zhang, Jinfang; Jia, Ding; Meng, Suci; Zaworotko, Michael J.; Cifuentes, Marie; Zhang, Chi; Humphrey, Mark


An ammonium–crown ether host–guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster–metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3]+ with different connection environments, pentanuclear clusters [WS4Cu4]2+, and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components

CollectionsANU Research Publications
Date published: 2016
Type: Journal article
Source: Chemical Communications
DOI: 10.1039/c5cc10076c


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