Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties **
An ammonium–crown ether host–guest supramolecular cation-templated synthetic methodology has been developed to construct a structurally unprecedented heterobicluster–metal coordination polymer (HCM-CP 1) based on tetranuclear clusters [WS4Cu3]+ with different connection environments, pentanuclear clusters [WS4Cu4]2+, and Cu+ building metal ions. HCM-CP 1 exhibits enhanced NLO properties, which may be ascribed to the incorporation of diverse building cluster components
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