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Mimicking enzymatic systems: Modulation of the performance of polymeric organocatalysts by ion-specific effects

Xu, Yun; Hua, Zan; Zhang, Jian; Yang, Jun; Cao, Zhonglin; Zhang, Dongyang; He, Lingxin; Craig, Vincent; Zhang, Guangzhao; Liu, Guangming


Like natural enzymatic systems, our study has demonstrated that the activity of the polymeric organocatalysts can be modulated by ion-specific effects via the combination of anion-specific salting-in/out effects and anion-specific polarization of hydrogen bonding induced stabilization of the transition state.

CollectionsANU Research Publications
Date published: 2016
Type: Journal article
Source: Chemical Communications
DOI: 10.1039/c5cc09959e


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