Mimicking enzymatic systems: Modulation of the performance of polymeric organocatalysts by ion-specific effects
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Xu, Yun; Hua, Zan; Zhang, Jian; Yang, Jun; Cao, Zhonglin; Zhang, Dongyang; He, Lingxin; Craig, Vincent; Zhang, Guangzhao; Liu, Guangming
Description
Like natural enzymatic systems, our study has demonstrated that the activity of the polymeric organocatalysts can be modulated by ion-specific effects via the combination of anion-specific salting-in/out effects and anion-specific polarization of hydrogen bonding induced stabilization of the transition state.
Collections | ANU Research Publications |
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Date published: | 2016 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/102886 |
Source: | Chemical Communications |
DOI: | 10.1039/c5cc09959e |
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01_Xu_Mimicking_enzymatic_systems%3A_2016.pdf | 1.99 MB | Adobe PDF | Request a copy |
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