A combined diffraction (XRD, electron and neutron) and electrical study of Na3MoO3F3
Na3MoO3F3, a member of the A 2BMVIO3F3 family of elpasolite-related oxyfluorides, has been prepared by the reaction of NaF with MoO3 at 650°C. It is shown by a combined X-ray, electron and neutron diffraction study, that the true symmetry of Na3MoO 3F3 is not monoclinic (pseudo-orthorhombic) as previously reported but instead triclinic (metrically rhombohedral) P1. The superstructure unit cell is given by a=-aR+bR, b=cR, c=(a R+bR+cR), when expressed with respect to the underlying rhombohedral...[Show more]
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|Source:||Journal of Solid State Chemistry|
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