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A combined diffraction (XRD, electron and neutron) and electrical study of Na3MoO3F3

Brink, Frank; Noren, Lasse; Goossens, Darren; Withers, Raymond; Liu, Yun; Xu, Chao-Nan

Description

Na3MoO3F3, a member of the A 2BMVIO3F3 family of elpasolite-related oxyfluorides, has been prepared by the reaction of NaF with MoO3 at 650°C. It is shown by a combined X-ray, electron and neutron diffraction study, that the true symmetry of Na3MoO 3F3 is not monoclinic (pseudo-orthorhombic) as previously reported but instead triclinic (metrically rhombohedral) P1. The superstructure unit cell is given by a=-aR+bR, b=cR, c=(a R+bR+cR), when expressed with respect to the underlying rhombohedral...[Show more]

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/102837
Source: Journal of Solid State Chemistry
DOI: 10.1016/S0022-4596(03)00303-7

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