Skip navigation
Skip navigation

The application of a monolithic triphenylphosphine reagent for conducting Ramirezgem-dibromoolefination reactions in flow

Roper, Kimberley A; Berry, Malcolm B; Ley, Steven V

Description

The application of a monolithic form of triphenylphosphine to the Ramirez gem-dibromoolefination reaction using flow chemistry techniques is reported. A variety of gem-dibromides were synthesised in high purity and excellent yield following only removal of solvent and no further off-line purification. It is also possible to perform the Appel reaction using the same monolith and the relationship between the mechanisms of the two reactions is discussed.

CollectionsANU Research Publications
Date published: 2013-09-02
Type: Journal article
URI: http://hdl.handle.net/1885/100842
Source: Beilstein Journal of Organic Chemistry
DOI: 10.3762/bjoc.9.207

Download

File Description SizeFormat Image
01_Roper_The_application_of_a_2013.pdfPublished Version716.77 kBAdobe PDFThumbnail


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  23 August 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator