The application of a monolithic triphenylphosphine reagent for conducting Ramirezgem-dibromoolefination reactions in flow
The application of a monolithic form of triphenylphosphine to the Ramirez gem-dibromoolefination reaction using flow chemistry techniques is reported. A variety of gem-dibromides were synthesised in high purity and excellent yield following only removal of solvent and no further off-line purification. It is also possible to perform the Appel reaction using the same monolith and the relationship between the mechanisms of the two reactions is discussed.
|Collections||ANU Research Publications|
|Source:||Beilstein Journal of Organic Chemistry|
|Access Rights:||Open Access|
|01_Roper_The_application_of_a_2013.pdf||Published Version||716.77 kB||Adobe PDF|
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