Co-ordinative activation of phosphaalkynes
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Bedford, Robin B.
Hill, Anthony F.
Jones, Cameron
White, Andrew J.P.
Wilton-Ely, James D.E.T.
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Abstract
The reactions of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S) with iodomethane provided the phosphaalkene complexes [Ru(PMe=CHBut)Cl(I)(CA)(PPh3)2] (I trans to phosphaalkene), with one example (A = O) having been crystallographically characterised.
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Journal of the Chemical Society - Dalton Transactions
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