Diyne Coordination Chemistry .3. on the Reactions of [ruclh(co)(pph3)3] with Bis(alkynyl)mercurials
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HILL, AF
HARRIS, MCJ
MELLING, RP
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The reaction of [RuClH(CO)(PPh3)3] with bis(alkynyl)mercurials [Hg(C = CR)2] (R = Ph, C6H4Me-4, nC4H9, CMe2OH) leads to the formation of the coordinatively unsaturated but-3-en-l-yn-3-yl complexes [Ru{C(C = CR) = CHR}Cl(CO)(PPh3)2].
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Polyhedron
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