X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
| dc.contributor.author | Hicks, Jamie | en |
| dc.contributor.author | Juckel, Martin | en |
| dc.contributor.author | Jones, Cameron | en |
| dc.date.accessioned | 2026-01-01T17:41:43Z | |
| dc.date.available | 2026-01-01T17:41:43Z | |
| dc.date.issued | 2021-10-07 | en |
| dc.description.abstract | The previously reported Mn-0-Mg-II bonded heterobimetallic compound [L+Mn-Mg((Mes)Nacnac)] (L+ = -N(Ar+)(SiPr3i),Ar+ = C6H2{C(H)Ph-2}(2)Pri-2,6,4;(Mes)Nacnac = [((NCMe)-N-Mes)(2)CH](-); Mes = mesityl) forms an adduct complex, [L+Mn-Mg(THF)((Mes)Nacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L+Mn-Mg((Mes)Nacnac)] to give the hydroxide bridged heterobimetallic, [L+Mn(mu-OH)(2)Mg((Mes)Nacnac)]. The Mn-0-Mg-II bonded heterobimtallic reductively disproportionates CO2, affording the carbonate bridged species, [{L+Mn(mu-CO3)Mg(THF) ((Mes)Nacnac)}(2)], in the presence of THF. The three new compounds have been crystallographically characterized. | en |
| dc.description.sponsorship | This research was supported by the Australian Research Council. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 6 | en |
| dc.identifier.issn | 0792-1241 | en |
| dc.identifier.other | WOS:000707533200001 | en |
| dc.identifier.other | ORCID:/0000-0001-9450-2594/work/172102896 | en |
| dc.identifier.scopus | 85117941134 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733801830 | |
| dc.language.iso | en | en |
| dc.source | Main Group Metal Chemistry | en |
| dc.subject | Carbonate | en |
| dc.subject | Heterobimetallic | en |
| dc.subject | Magnesium | en |
| dc.subject | Manganese | en |
| dc.subject | Metal-metal bond | en |
| dc.title | X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 255 | en |
| local.bibliographicCitation.startpage | 250 | en |
| local.contributor.affiliation | Hicks, Jamie; Monash University | en |
| local.contributor.affiliation | Juckel, Martin; Monash University | en |
| local.contributor.affiliation | Jones, Cameron; Monash University | en |
| local.identifier.citationvolume | 44 | en |
| local.identifier.doi | 10.1515/mgmc-2021-0027 | en |
| local.identifier.pure | edc6dc02-eec9-4eb8-a3ed-a76c4c13ab46 | en |
| local.identifier.url | https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000707533200001&DestLinkType=FullRecord&DestApp=WOS_CPL | en |
| local.identifier.url | https://www.scopus.com/pages/publications/85117941134 | en |
| local.type.status | Published | en |