Rigid, biconical hydrogen-bonded dimers that strongly encapsulate cationic guests in solution and the solid state
| dc.contributor.author | Smith, Jordan N. | en |
| dc.contributor.author | Ennis, Courtney | en |
| dc.contributor.author | Lucas, Nigel T. | en |
| dc.date.accessioned | 2025-06-11T15:37:49Z | |
| dc.date.available | 2025-06-11T15:37:49Z | |
| dc.date.issued | 2021-08-11 | en |
| dc.description.abstract | The octol of a new rigid, tetraarylene-bridged cavitand was investigated for self-assembly behaviour in solution.1H and DOSY NMR spectroscopic experiments show that the cavitand readily dimerizes through an unusual seam of interdigitated hydrogen-bonds that is resistant to disruption by polar co-solvents. The well-defined cavity encapsulates small cationic guests, but not their neutral counterparts, restricting the conformation of sequestered tetraethylammonium in solution and the solid state. | en |
| dc.description.sponsorship | Financial support was provided by The MacDiarmid Institute for Advanced Materials and Nanotechnology, and the Marsden Fund Council, managed by the Royal Society Te Ap¯arangi, New Zealand. J. N. S. thanks the University of Otago for the award of a PhD scholarship. C. E. thanks the National Computational Infrastructure (NCI: supported by the Australian Government) for high performance computing resources and services provided via project grant ay7. Financial support was provided by The MacDiarmid Institute for Advanced Materials and Nanotechnology, and the Marsden Fund Council, managed by the Royal Society Te Ap?rangi, New Zealand. J. N. S. thanks the University of Otago for the award of a PhD scholarship. C. E. thanks the National Computational Infrastructure (NCI: supported by the Australian Government) for high performance computing resources and services providedviaproject grant ay7. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 6 | en |
| dc.identifier.issn | 2041-6520 | en |
| dc.identifier.other | ORCID:/0000-0002-7009-6525/work/168891842 | en |
| dc.identifier.scopus | 85115095616 | en |
| dc.identifier.uri | http://www.scopus.com/inward/record.url?scp=85115095616&partnerID=8YFLogxK | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733758788 | |
| dc.language.iso | en | en |
| dc.rights | Publisher Copyright: © The Royal Society of Chemistry 2021. | en |
| dc.source | Chemical Science | en |
| dc.title | Rigid, biconical hydrogen-bonded dimers that strongly encapsulate cationic guests in solution and the solid state | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 11863 | en |
| local.bibliographicCitation.startpage | 11858 | en |
| local.contributor.affiliation | Smith, Jordan N.; University of Otago | en |
| local.contributor.affiliation | Ennis, Courtney; University of Otago | en |
| local.contributor.affiliation | Lucas, Nigel T.; University of Otago | en |
| local.identifier.citationvolume | 12 | en |
| local.identifier.doi | 10.1039/d1sc01802g | en |
| local.identifier.pure | 28b7d475-c794-4e84-8745-30cff2049107 | en |
| local.identifier.url | https://www.scopus.com/pages/publications/85115095616 | en |
| local.type.status | Published | en |