Redox flexibility in a germanium hydride manifold: hydrogen shuttling <i>via</i> oxidative addition and reductive elimination
| dc.contributor.author | Caise, Alexa | en |
| dc.contributor.author | Hicks, Jamie | en |
| dc.contributor.author | Heilmann, Andreas | en |
| dc.contributor.author | Aldridge, Simon | en |
| dc.date.accessioned | 2026-01-01T17:42:24Z | |
| dc.date.available | 2026-01-01T17:42:24Z | |
| dc.date.issued | 2023 | en |
| dc.description.abstract | We report the synthesis of a trimetallic mixed-valence Ge(i)/Ge(ii)/Ge(iii) trihydride, which presents a structural novel motif among systems of the type (XMH)(n) (M = group 14 metal). In terms of reactivity (Ar-NiPr2)GeGe(Ar-NiPr2)(H)Ge(Ar-NiPr2)(H)(2) can act as a source of both the Ge(ii) and Ge(iv) hydrides via Ge-H reductive elimination from the central metal centre involving two different regiochemistries. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 4 | en |
| dc.identifier.issn | 1359-7345 | en |
| dc.identifier.other | WOS:000993916100001 | en |
| dc.identifier.other | PubMed:37222547 | en |
| dc.identifier.other | ORCID:/0000-0001-9450-2594/work/172102892 | en |
| dc.identifier.scopus | 85161653443 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733801904 | |
| dc.language.iso | en | en |
| dc.source | Chemical Communications | en |
| dc.subject | Tin(ii) hydride | en |
| dc.subject | Isomeric forms | en |
| dc.subject | Activation | en |
| dc.subject | Dihydrogen | en |
| dc.subject | Digermyne | en |
| dc.subject | Bond | en |
| dc.title | Redox flexibility in a germanium hydride manifold: hydrogen shuttling <i>via</i> oxidative addition and reductive elimination | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 7254 | en |
| local.bibliographicCitation.startpage | 7251 | en |
| local.contributor.affiliation | Caise, Alexa; University of Oxford | en |
| local.contributor.affiliation | Hicks, Jamie; University of Oxford | en |
| local.contributor.affiliation | Heilmann, Andreas; University of Oxford | en |
| local.contributor.affiliation | Aldridge, Simon; University of Oxford | en |
| local.identifier.citationvolume | 59 | en |
| local.identifier.doi | 10.1039/d3cc01411h | en |
| local.identifier.pure | 18f7e5f2-a6a3-4ceb-82be-e5ae698b21b3 | en |
| local.identifier.url | https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000993916100001&DestLinkType=FullRecord&DestApp=WOS_CPL | en |
| local.identifier.url | https://www.scopus.com/pages/publications/85161653443 | en |
| local.type.status | Published | en |