Coupling Versus Substitution of Coordinated Ethylene with Iminooxosulfanes - Crystal-structure of [os(ch2ch2s(nso2c6h4me-4)o)cl(no)(pph3)2]
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Herberhold, Max
Hill, Anthony F.
Clark, George R.
Rickard, Clifton E.F.
Roper, Warren R.
Wright, Anthony H.
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Abstract
The osmium ethylene complex [OsCf-(NO)(C2H4)(PPh3)2] reacts with ((p-tolylsulfonyl)imino)oxo-λ4-sulfane (O=S=NSO2C6H4Me-4) by either substitution of or electrophilic attack at the coordinated ethylene ligand to provide respectively [OsCI(NO)(η2-OSNSO2G6H4Me-4)(PPh3)2] or the structurally characterized osmacycle [Os{CH2CH2S(=NSO2C6H4Me-4)O}CI-(NO)PPh3)2].
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Organometallics
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