Direct characterisation of mJ = ±15/2 ground state in octahedral Dy(III) single-molecule magnets
| dc.contributor.author | Parmar, Vijay S. | en |
| dc.contributor.author | Gransbury, Gemma K. | en |
| dc.contributor.author | Corner, Sophie C. | en |
| dc.contributor.author | Chou, Wei-Hao | en |
| dc.contributor.author | Hill, Stephen | en |
| dc.contributor.author | Winpenny, Richard E. P. | en |
| dc.contributor.author | Chilton, Nicholas F. | en |
| dc.contributor.author | Mills, David P. | en |
| dc.date.accessioned | 2026-02-27T10:41:02Z | |
| dc.date.available | 2026-02-27T10:41:02Z | |
| dc.date.issued | 2025-05-01 | en |
| dc.description.abstract | Two heteroleptic octahedral Dy(III) cis-aryloxide complexes, [Dy(OPh*)2(THF)3X] HOPh* = 2,6-bis(diphenyl-methyl)-4-tert-butylphenol; X = Cl (1), Br (2), have been characterised by multi-frequency electron paramagnetic resonance (EPR) spectroscopy to determine gz = 18.9(1) for 1 and 18.3(6) for 2. These are rare examples of Dy(III) single-molecule magnets that have observable EPR spectra. | en |
| dc.description.sponsorship | A portion of this work was performed at the National High Magnetic Field Laboratory, which is supported by the National Science Foundation Cooperative Agreement No. DMR-2128556 and the State of Florida. We thank the University of Manchester (President’s Doctoral Scholarship), the UK EPSRC (EP/ P002560/1, EP/R011079/1), the ERC (ERC-2019-StG-851504, ERC-2019-CoG-816268, ERC-2017-AdG-786734) and the Royal Society (URF191320) for funding. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 5 | en |
| dc.identifier.issn | 1477-9226 | en |
| dc.identifier.other | Bibtex:parmar_direct_2025 | en |
| dc.identifier.scopus | 105003754874 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733806712 | |
| dc.language.iso | en | en |
| dc.provenance | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. | en |
| dc.rights | © 2025 The Authors | en |
| dc.source | Dalton Transactions | en |
| dc.title | Direct characterisation of mJ = ±15/2 ground state in octahedral Dy(III) single-molecule magnets | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 7620 | en |
| local.bibliographicCitation.startpage | 7616 | en |
| local.contributor.affiliation | Parmar, Vijay S.; University of Manchester | en |
| local.contributor.affiliation | Gransbury, Gemma K.; University of Manchester | en |
| local.contributor.affiliation | Corner, Sophie C.; University of Manchester | en |
| local.contributor.affiliation | Chou, Wei-Hao; Florida State University | en |
| local.contributor.affiliation | Hill, Stephen; Florida State University | en |
| local.contributor.affiliation | Winpenny, Richard E. P.; University of Manchester | en |
| local.contributor.affiliation | Chilton, Nicholas F.; Chemistry Research, Research School of Chemistry, ANU College of Science and Medicine, The Australian National University | en |
| local.contributor.affiliation | Mills, David P.; University of Manchester | en |
| local.identifier.citationvolume | 54 | en |
| local.identifier.doi | 10.1039/D5DT00862J | en |
| local.identifier.pure | 266bbcc5-bbce-42b9-be2c-344816d7b828 | en |
| local.type.status | Published | en |
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