Mixed-metal cluster chemistry. 4.<sup>1</sup> Synthesis and X-ray crystal structure of Cp<sub>3</sub>W<sub>3</sub>Ir<sub>4</sub>(μ-H)(CO)<sub>12</sub>
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Waterman, Susan M.
Humphrey, Mark G.
Hockless, David C.R.
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Heating Cp2W2Ir2(CO)10 with triphenylamine in refluxing tetrahydrofuran affords Cp3W3Ir4(μ-H)-(CO)12 (1) in poor yield; an X-ray structural study reveals that the molecule consists of a trigonal bipyramidal CpW{Ir(CO)2}4 unit bicapped by CpW(CO)2 fragments.
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Organometallics
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