Thioacyl complexes of molybdenum and tungsten
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Cook, Darren J.
Hill, Anthony F.
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The reactions of a range of alkylidyne complexes of molybdenum and tungsten [M(≡CR)Ln] with 2-methylthiirane provide the first thioacyl complexes [M(η2-SCR)Ln] of these elements, which serve as precursors for complexes bearing dithiocarboxylate, thioselenocarboxylate, thiolatocarbene and α-thioalkyl ligands and thioacyl-bridged binuclear complexes.
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Chemical Communications
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