Metal Actuated Ring Translocation Switches in Water
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Yin, Hang
Rosas, Roselyne
Gigmes, Didier
Ouari, Olivier
Wang, Ruibing
Kermagoret, Anthony
Bardelang, David
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Abstract
Among a series of metal ions in water, silver is the only one to remotely and reversibly switch cucurbit[7]uril (CB[7]) movements (translocation or uptake) on a rigid and linear three-station viologen-phenylene-imidazole (V-P-I) derivative, avoiding undesired pH actuation. 1H NMR, UV-vis spectroscopy, mass spectrometry, ITC, and modeling were combined to show that ring translocation or uptake along a molecular thread is possible in water by Ag+ as a metal stimulus.
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Organic Letters
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