The coordination chemistry of iminooxosulphuranes: III. Synthesis of the ruthenium complexes [Ru(OC)(PPh3)2(L)(OSNR)] (L = CO, CNtBu, CNC6H3Me2-2,6; R = C6H4Me-2, C6H4Me-4)
| dc.contributor.author | Herberhold, Max | en |
| dc.contributor.author | Hill, Anthony F. | en |
| dc.date.accessioned | 2026-01-12T08:01:02Z | |
| dc.date.available | 2026-01-12T08:01:02Z | |
| dc.date.issued | 1989-05-23 | en |
| dc.description.abstract | The tris(phosphine) complexes [Ru(CO)(PPh3)3(L)] (L = CO, CNtBu, CNC6H3Me2-2,6) react with iminooxosulphuranes. RNSO, (R = C6H4Me-2, C6H4Me-4) by a displacement of one labile phosphine ligand to provide [Ru(CO)(PPh3)2(L)(OSNR)]. Spectroscopic data indicate that the heterocumulenes are bound to ruthenium through both nitrogen and sulphur. Sulphur dioxide coordinates in a similar bidentate mode, through sulphur and oxygen, in the complexes [Ru(CO)(PPh3)2(L)(SO2)] that are obtained upon treatment of the corresponding tris(phosphine) precursors with gaseous sulphur dioxide. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 7 | en |
| dc.identifier.issn | 0022-328X | en |
| dc.identifier.other | ORCID:/0000-0003-2167-0604/work/167652073 | en |
| dc.identifier.other | WOS:A1989U780000012 | en |
| dc.identifier.scopus | 0004918019 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733804113 | |
| dc.language.iso | en | en |
| dc.source | Journal of Organometallic Chemistry | en |
| dc.title | The coordination chemistry of iminooxosulphuranes: III. Synthesis of the ruthenium complexes [Ru(OC)(PPh3)2(L)(OSNR)] (L = CO, CNtBu, CNC6H3Me2-2,6; R = C6H4Me-2, C6H4Me-4) | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 117 | en |
| local.bibliographicCitation.startpage | 111 | en |
| local.contributor.affiliation | Herberhold, Max; University of Bayreuth | en |
| local.contributor.affiliation | Hill, Anthony F.; University of Warwick | en |
| local.identifier.citationvolume | 368 | en |
| local.identifier.doi | 10.1016/0022-328X(89)80123-8 | en |
| local.identifier.pure | cc547490-4a50-4a2f-bba7-fb3429a6b867 | en |
| local.identifier.url | https://www.scopus.com/pages/publications/0004918019 | en |
| local.type.status | Published | en |